I thought that the BP measures all measured volume? It thought that when my adjustable measure was set to say 40 grains it was by volume. I've read over and over on some of these forums that any talk of grains in relation to muzzleloaders was by volume and not weight since they don't coincide. Is this not correct?
Yes, that's correct.
Black powder charges are specified using a volume metric called 'grains'.
Smokeless powder charges are specified using a mass metric called 'grains'.
If you know what kind of powder you're measuring, and you damn well better, then you know whether you are using the volume metric or the mass metric.
If you are using real black powder, there's really no practical difference between the mass and volume metric results; 100 grains (mass) of real black powder is very nearly (but not exactly) 100 grains (volume). If you measure out 100 grains (volume) of real black powder using a volume measure and then weigh that charge any variation from 100 grains (mass) is most likely due to an inaccurate volume measure - they are notoriously inaccurate devices.
People who weigh their real black powder charges do so for precision; you will get more consistent results using weight. Yes, the slug gun guys use a scale and weigh their charges on the line. Most, but not all, of the guys I observe on the offhand line use a volume measure. None of the people on the woods walk weigh their charges. When shooting for pleasure at the range I use a volume measure; when shooting for precision I weigh my charges in advance and use loading tubes on the line.
The black powder community has used this faux metric called 'grains by volume' for many, many years as a matter of convenience, counting on the nearly 1 for 1 relationship between weight and volume of real black powder. That doesn't make it 'wrong' or 'right', it's just what we do.
Then some jerk had to come along and introduce
synthetic black powder and throw the whole thing into a cocked hat. The smokeless powder community has been well aware for years that different powders have different densities, so when specifying a load it is necessary to include the brand of powder; 3 grains of Unique will not give the same results as 3 grains of Bullseye (I think). However, the
synthetic black powders (excepting, of course, 777 - there always has to be an exception) were designed to give the same results as real black powder when measured by volume. So, the black powder folks just continue to use their volume metric, driving some folks mad with frustration.