Since you called it a new build on a Quarter Circle 10 Lower, can we assume this is a 9mm AR variant?
This is what we know: The bullet is still in the barrel, and the bolt came back while there was still excessive pressure in the chamber, causing case failure. (Separated case, big fireball, mag destruction are all signs of this)
It's worth remembering that a 9mm AR is a blowback weapon so the bolt doesn't lock, and the normal safety of an AR's firing pin being too short to poke through an unlocked bolt doesn't apply here.
So a couple things could have happened:
The round before it blew up could have been the squib your gunsmith mentioned. The obstructed bore would have raised chamber pressure, opened the bolt and blown out the case on the next round. If there are two projectiles in the bore when you hammer them out, this is the likely cause.
The round could have been overcharged. Again, high chamber pressure would have opened the bolt early, rupturing the case and leaving the projectile stuck in the bore.
The gun's spring, buffer and bolt could be set up improperly. Since nothing locks the bolt in battery, if the recoil system is to light there's not enough inertia to hold the bolt closed until the bullet leaves and pressures drop. Again, bolt retracts early, case fails, pressure vents and the bullet is left stuck in the barrel.
As Tirod mentioned the bolt could have bounced right as you pulled the trigger. This would have required extremely [un]lucky timing on pulling the trigger. Were you shooting fast?
Something could have set the primer off early. Depending on the hammer design, it might be possible (but unlikely, I'd have to check, and my 9mm AR isn't handy right now) for a hammer that missed the disconnector to follow the bolt home and press on the firing pin before the bolt is all the way closed. This theory is kinda flimsy, and IMHO unlikely, but I guess it's possible.
A dirty chamber could have held the new round far enough out of the chamber that the case had no support, but far enough in that the hammer could still hit the firing pin. (Again, that's probably a pretty narrow window given the geometry of the hammer and back of the bolt.) Primer ignites, case fails, pressure vents, yada, yada.
There's probably some other things that could cause it as well. I think it's pretty unlikely that the round went off early, as that bolt/hammer geometry is pretty easy to control, and would be designed out of the gun (I hope. There are a number of AR hammers out there, and we don't know which you have.)
It's more likely, in my opinion, that the bolt opened early, while chamber pressure was too high, and the case ruptured from there. There's nothing holding it closed except inertia from the bolt and buffer. So either a bore restriction/obstruction from the previous round, or the ammo was too hot for the installed bolt/buffer/spring. Check those first.