Pink cases after washing

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Sky King

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Just finish washing some 9mm and 38 Spec cases with hot water, Lemi Shine and Dawn. The first bucket of 9mm's cleaned up just fine, the second bucket of 9mm's had some cases turning pink. Made no difference which brand, Win, FC and Speer. The third bucket of 38 Spec. again cleaned up just fine.
What caused the pink cases, after drying will tumbling remove the pink and are they ok to reload?
 
Yes, they'll be fine to reload, no answer for the color change. Yes, put some Nu Finish car polish in with the tumbling media, all will be fine after about an hours time. It'll all come out in the wash. LOL
 
The pink is the copper that is left after the zinc is dissolved on the surface of the brass. If they polish up OK and the pink is gone they were not damaged a lot and probably still usable with a resulting shorter number of reloads till they split. If still pink you could try loading up a couple handfulls and trying them several times but I would not just go and reload them all until the test batch proves reliable for a few reloads first. I would say too much LemmyShine or left in the mix too long.
 
I ultrasonically cleaned some cases today and rinsed them in baking soda and water. I got the great idea to dry them outside in the sun and when I got home they had a rainbow look to them.
 
What Frogo said, either too much Lemi or left in it too long. Tumble it and it should be fine. Just call it your Hello Kitty Load. :D
 
Hogpauls +1
The acid leaches the zinc out a little. Use less or don't leave it in the solution as long.

I use laundry soap and white vinegar (much cheaper) and it can do the same. My solution works fine when used for 15 mins, longer and the cases will start to show some "pink".

Polish them up and shoot 'em.
 
De-zinc for the win !

+1 on white vinegar....cheaper, more uses, and premixed. Plus, what other reloading supplies can you use for makeshift salad dressing ?
 
Again, I use vinegar and nothing once for 15 minutes maximum for the life of the case, and only for the worst of cases, I have purchased thousands of cases that were best described as patina-ed. I believe a steady diet of acid in the cleaning solution is a bad habit, again, in the old days instructions for cleaning cases in old reloading manuals suggested the old government formula, 2% H2S03 for a maximum of 2-3 minutes followed by rinsing in clean boiling water twice.

And now I wonder? Is it the new methods for cleaning cases that cleans or is it the acid? Again, I can clean cases with vinegar and nothing, I can cut down on the time by agitating.

I used vinegar to reduce tumbling time, time was reduced from 4 days to 2 hours.

Then when I want to show off ‘or’ I have 20 cases to load and do not want to spend all that tumbling I use home made spinners.

F. Guffey
 
You're probably right, I think I left them in the solution too long and too strong.

Thanks
 
“I think I left them in the solution too long and too strong”.

Sky King, vinegar hovers around 5% acid, vinegar can be reduced by adding water, when using straight 5% +or- vinegar the reloader can experiment with the effect the acid has on a case, fill a small glass ‘whatever’ with vinegar then add as many cases as the reloader chooses, then check the time of exposure in hours and days.

Again, I choose 15 minutes maximum, if left in solution for 30 minutes the cases appear to look like I forgot them, try leaving the cases in the solution for 2 days.

I collect old tools, for most I apply the leaver policy, I leaver the way I founder, but there are times rust does not enhance to appearance so I use vinegar on cast iron and rusty tools, most tools and cast iron submerged in vinegar for 8 to 12 hours come out of the solution with no to little rust with no etching, In my opinion it beats grinding and wire brushing. I have used stronger solutions of acid, time is reduced to minutes and there is too great a chance something will go wrong. I know, there is a gel that can be used, I have time, and vinegar is not as expensive. And if I want to take more time, I can reduce the solution with water.

Back to methods? How well does other methods work without the acid solution? Again, I can clean cases in vinegar, the worst of cases, in 15 minutes or less, clean enough to load with out the ss pins and the expense of replacing all of my tumbling equipment.

Then there was ceramic, replace corm/walnut with ceramic, and that change smoked a few motors, I was not in that line, it reminded me of a book written about the adventures of an Old Sea Captain that died and went to Heaven.

F. Guffey
 
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If you put about a 6-8 ozs of 15% white vinegar in one gallon of water, add 1/4 cup of liquid laundry soap and a teaspoon of non-iodized salt.; in 15 minutes the cases are ready to load and look very good "inside" and out. If you deprime first, it cleans up the primer hole too.

I rinse with garden hose nozzle set to the "stun setting" after pouring the solution into another container for reuse for a few thousand more 9mm cases.

Your tumbling media will stay clean and crud-free for a looong time.
 
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