So you are talking about the edges of the slot in the trigger guard housing (not the frame) that the trigger sticks down through? Or the top edge of the trigger itself?
Either way, to smooth those areas adequately you are probably going to need to disassemble the trigger guard group completely to take the trigger out so you can get at the edges of the trigger cut out in the trigger guard housing. This might seem a little intimidating if you have never done it before, but is really not too hard. Refer to the SP101 trigger job guide I cited earlier for instructions and photos. Just be careful not to lose the pawl spring and cylinder latch spring during assembly and disassembly and don't get them mixed up because they are different sizes.
As was said, a lot of people find the edges of the SP100 trigger (and the hammer spur) too sharp. As the trigger and hammer are stainless, you can round the edges at will using files and then smooth with fine sandpaper and metal polish. For the edges of the trigger guard cutout you may be able to knock the edge off with a very thin file, or use sandpaper if you don't have such a file. If you mask the portions of the trigger guard housing that show with tape, you should be able to do this without removing much bluing from the visible part of the trigger guard housing.