It’s been done for years!
“Pumpkin” ball is backwoods slang for a rifled slug. They have ridges formed by swaging the soft hollow lead slug with spiral ridges in an attempt to attain spin stabilization.
Round ball as in “musket” balls work well in smooth bore shot guns to 40-50yds.
Your.535” RB will work well in a 28ga shot shell. There are various techniques available to accomplish this. Ranging from cutting off the crimp from a loaded factory shot shell and inserting the round ball (least satisfactory), to using over shot, card, and cushion wads to build up a wad column and custom roll crimping the hulls.
The round ball loads shoot especially well in my Savage M220 rifled bore bolt action. I use a .615” cast round ball in a 7/8oz plastic wad with a filler. Accurate to 60-70yds.
For much more detailed information, go to
www.gunloads/castboolits.com
There is a dedicated thread to loading for shotguns.
As to your other question of how many round ball in a shot shell; it depends. A 28ga likely will hold 2 0.535” RB. Likewise, a 20ga will hold 2- 0.615” RB. and a 12ga, two .685”.
I load a 3” .410 load with 4-buckshot. A .360” in the bottom of the shot cup, and 3- .375” RB. I use a 7/16” wad to enclose the load.