My thinking is that over an extended period, the other unopened jugs will stay fresh, and are of the same lot number, and won't get lighter, over time, as an open 8# jug would.
The shooting and reloading community get their primary information from Gunwriters who are not technically educated. There are no educational requirements to be a gunwriter and the vast majority of them maybe have a French degree. They are also not in the business of education, they are in the business of sales. The shooting industry is not interested in educating the public about problems with ammunition because it is far more profitable to keep you fat, dumb, and happy. If you learned that gunpowder has a shelf life, and therefore ammunition has a shelf life, you the consumer might get picky. You might not pay full price for 10, 20, year old ammunition and gunpowder.
Lacking technical commentary what I have seen is an interesting drift from good advice given long ago. That is gunpowder should be stored in a cool and dry place. Over time this has morphed into weird ideas such as gunpowder will last forever if the containers are never opened.
Whether or not you open your jug of gunpowder, it is still breaking down. Gunpowder is a high energy compound that was breaking down to a low energy compound from the day it was made. As I have written in other posts, the primary enemy to gunpowder is heat. Exposure to temperatures over 86 F will accelerate the deterioration of gunpowder. Exposure to ions will deteriorate gunpowder. Air has lots of covalent molecules called water and that oxygen atom on the end reacts with gunpowder, just as an ionic molecule will. Therefore, keeping gunpowder dry is a good thing. Won't slow gunpowder deterioration but will not accelerate the rate of deterioration.
I have written extensively on old, deteriorated gunpowder. While the collective shooting community is in denial about this, old gunpowder gets dangerous with age for a number of reasons. These are threads which I provided information on old gunpowder and old ammunition.
Old Powder Caused Fire!
http://www.thehighroad.org/showthread.php?t=788841
Old powder
http://www.thehighroad.org/showthread.php?t=787843
Shelf life of reloads?
http://www.thehighroad.org/showthread.php?t=758305
Look at the pictures in this thread:
Has anyone else had Vihtavuori N140 corrode in loaded ammo?
http://www.falfiles.com/forums/showthread.php?p=3745264
The green corrosion inside the brass cases came from nitric acid gas outgassing from old deteriorated gunpowder. This nitric acid gas also attacks the brass causing case splits. When the corrosion is extreme it will cause pin hole through corrosion of the case. I have seen all of these.
Gunpowder lifetime is unpredictable, a rule of thumb is 20 years for double based, 45 years for single based. Some fails sooner. Hardly any gunpowder is safe past 45 years. Old gunpowder in bulk will autocombust. In my opinion, keeping gunpowder in small containers is probably safer than bigger containers. Autocombustion is an undesirable event, but maybe if one of those small containers auto combusts, the chance of the house burning down around you is less than if a kegger goes off. Who knows? and regardless, big keg, little pounder, if one goes off it is all bad.
People post pictures of their WW2 powder, kegs that they have stored in their house, nicely sealed against the air, and therefore, it will last forever. They are wrong. I hope they don't wake up to a house of flames.