I had a few similar looking events using Re#7, WW Large rifle primers in some trapdoor loads with a 45/70. Some did not fire and some hangfired. I pulled those that that did not fire and the powder looked just like that. As these were virgin brass I always figured that there was some oily contamination in the new brass. The loads always worked fine when loaded after that. Looks like I might have just had some bad primers?
RJ
RJ