It is brass from a military round, it was probably loaded to 5.56 pressures. As it stand now it is both 5.56 and 223 brass as they are identical in external dimensions and are 100% interchangeable. FL size it and load it to 223 pressures and it becomes 223 brass, FL size it and load it to 5.56 pressures and it has become 5.56 brass.
Internal case capacity may vary from manufacturer to manufacturer, but in the 223 the majority of military brass has more case capacity than civilian(223) brass. LC having the highest case capacity in most instances.