Every "solvent" I ever tried seemed to remove some sort of fouling that the others didn't. A blackpowder range I frequented in the 90's had local shooters that commonly used the green scented alcohol to clean their rifles.
These were almost always "round ball" barrels, very long with slow twists, 50-58 caliber. Also, we strictly used vegetable based lube on our patches. I liked vegetable shortening on mine.
Some of the guys were real accuracy nuts and would swab with soapy water followed by clean water followed by alcohol followed by dry patches..until the bore was clean and dry. Fire a couple of caps in the clean bore, reload, and then follow with a tight fitting alcohol patch before the next shot. Some patched so tightly they used a small mallet to start the patched ball in the bore.
While I wasn't quite as diligent I did experiment around with it and found I liked to use a pot of boiling hot soapy water for my initial cleaning. Since my rifles had hooked breeches I would submerge the nipple in the pot and run a tightly patched jag up and down which would pull a full barrel of soapy water up into the bore and shove it back out with considerable force.
Scrub with a bore brush and repeat. Then follow with rinse in boiling hot watere only. Let dry.
Run soppy firm fitting 91% Rubbing Alcohol or Denatured Alcohol patches changing out patches until clean. Let dry.
Run WD-40 soaked patches repeatedly changing until clean. (this seemed to remove sulphur deposits the other methods hadn't phased.) Follow with dry patches until no residue evident.
Occassionally followed with Hoppes #9. (This removed other trace deposits the other methods didn't) Followed again with dry patches.
Finally followed with 3-n-1 oil firm fitting patch run in & out a few times before putting it away.
Before going shooting I'd clean with Coleman fuel to cut the oil and then with Alcohol to clean the petroleum out.
I wouldn't do all of this everytime, just when I was putting it away for a while.
Some guys never used any petroleum based products and did their final lube before storage with corn oil. I couldn't quite bring myself to do that but clearly more than one thing works.
Take it for whatever you wish but I suggest you try some things to find out for yourself.
Kindest regards,
TB